Raphael RaptisProfessor

106 Jessica M. Lopez Pla, Athanassios K. Boudalis, Joshua Telser and Raphael G. Raptis, "Chromium(III)-pyrazole complexes. X-Ray crystal structures, 1H NMR investigation of ligand fluxional behavior and EPR studies", Inorg. Chim. Acta, 2020, 502, 119299.

105 Yiannis Sanakis, Michael Pissas, J. Krzystek, Andrew Ozarowski, Joshua Telser, Raphael G. Raptis "Ferromagnetically-Coupled, Triangular, [Bu4N]2[CuII3(μ3-Br)2(μ-4-O2N-pz)3Br3] Complex Revisited: The Effect of Capping Halide on Spin Relaxation Properties", Polyhedron, 2020, 177, 114258.

104 Konstantinos A. Lazarou, Indranil Chakraborty, Raphael G. Raptis, "Re-investigation of an octanuclear iron-oxo complex supported by 4-tbutyl-pyrazolido ligands", Polyhedron, 2019, 171, 41-45.

103 Kaige Shi, Logesh Mathivathanan, Athanassios K. Boudalis, Philippe Turek, Indranil Chakraborty, Raphael G. Raptis, "Nitrite Reduction by Trinuclear Copper Pyrazolate Complexes: An Example of a Catalytic, Synthetic Polynuclear NO Releasing System", Inorg. Chem., 2019, 58, 7537-7544.

102 Konstantinos A. Lazarou, Karilys Gonzalez-Nieves, Indranil Chakraborty, Raphael G. Raptis, "Spontaneous Resolution by Crystallization of an Octanuclear Iron(III) Complex Using Only Racemic Reagents", Angew. Chem. Int. Ed., 2019, 58, 7324-7328.

101 David I. Kreiger, Logesh Mathivathanan, Raphael G. Raptis, "Coordination polymers based on pyrazole-4-carboxaldehyde-containing Cu3N6 metallacycles as building units", CrystEngComm, 2019, 21, 3047-3055.

100 Shambhu Kandel, Veerasamy Sathish, Logesh Mathivathanan, Alexander N. Morozov, Alexander M. Mebel, Raphael G. Raptis, "Aggregation induced emission enhancement (AIEE) of tripodal pyrazole derivatives for sensing of nitroaromatics and vapor phase detection of picric acid", New J. Chem., 2019, 43, 7251-7258.

99 Kaige Shi, Logesh Mathivathanan, Vadym A. Drozd, Raphael G. Raptis, "Three topological isomers of 1D- and 2D-coordination polymers consisting of tricopper pyrazolate SBUs and 4,4'-trimethylenedipyridine linkers: Effect of pressure on the structure", Cryst. Growth Des., 2019, 19, 381-390.

98 Shambhu Kandel, Jenny Stenger-Smith, Indranil Chakraborty, Raphael G. Raptis, "Synthesis and X-ray crystal structures of a family of dinuclear silver(I) pyrazolates: Assessment of their antibacterial efficacy against P. aeruginosa with a soft tissue and skin infection model", Polyhedron, 2018, 154, 390-397.

97. Soma Das, Kenia Parga, Indranil Chakraborty, Arthur D. Tinoco, Yamixa Delgado, Paola M. Lopez, Lauren Fernandez Vega, Yiannis Sanakis, Sukhen Ghosh, Jim Bankson, Jim Klostergaard, Ricardo Gonzalez-Mendez, Raphael G. Raptis, "Magnetic resonance imaging contrast enhancement in vitro and in vivo by octanuclear iron-​oxo cluster-​based agents", J. Inorg. Biochem., 2018, 186, 176-186.

96. Logesh Mathivathanan, Athanassios K. Boudalis, Philippe Turek, Michael Pissas, Yiannis Sanakis, Raphael G. Raptis, "Interactions between H-​bonded [CuII3(μ3-​OH)​] triangles; a combined magnetic susceptibility and EPR study", Phys. Chem. Chem. Phys., 2018, 20, 17234-17244.

95. Alan J. Rodriguez-Santiago, Nicole Cortes, Khoa Pham, Jorslava Miksovska, Raphael G. Raptis, "4,​4'-​Dihydroxy-​2,​2'-​bipyridine complexes of Co(III)​, Cu(II) and Zn(II)​; structural and spectroscopic characterization", Polyhedron, 2018, 150, 60-68.

94. Ksenija Babic-Samardzija, Peter Baran, Roman Boca, Radovan Herchel, Raphael G. Raptis, Carmen L. Velez, "Structural and magnetic susceptibility study of an octanuclear MnIII-​oxo-​pyrazolido complex", Polyhedron, 2018, 149, 142-147.

93. Logesh Mathivathanan, Guang Yang, Fenfei Leng, Raphael G. Raptis, "Crystal structure and conformational analysis of doxorubicin nitrate", Acta Crystallogr. Sect. E Struct. Commun. 2018, 73, 400-405.

92. Tosin M. Jonah, Logesh Mathivathanan, Alexander N. Morozov, Alexander M. Mebel, Raphael G. Raptis, Konstantinos Kavallieratos, "Remarkably selective NH4+ binding and fluorescence sensing by tripodal tris(pyrazolyl) receptors derived from 1,3,5-triethylbenzene:structural and theoretical insights on the role of ion pairing", New J. Chem. 2017, 41, 14835-14838 (10.1039/c7nj03213g)

91. Athanassios K. Boudalis, Guillaume Rogez, Benoit Heinrich, Raphael G. Raptis, Philippe Turek, “Towards ionic liquids with tailored magnetic properties: bmim+ salts of ferro- and antiferromagnetic CuII3 triangles”, Dalton Trans. 2017, 46, 12263-12273 (10.1039/c7dt02472j).

90. Evgen V. Govor, Yiannis Sanakis, Raphael G. Raptis, “Synthesis of pyrazole (hemi)aminals via the cleavage of saturated aliphatic ether C-O bonds in the presence of ferric halides”, New J. Chem. 2017, 41, 2220-2223 (10.1039/c6nj03822k).

89. Evgen V. Govor, Karrar Al-Ameed, Indranil Chakraborty, Carla S. Coste, Olena Govor, Yiannis Sanakis, John E. McGrady, Raphael G. Raptis, “A Redox-Induced Spin-State Cascade in a Mixed-Valent Fe3(μ3-O) Triangle”, Angew. Chem. Int. Ed., 2017, 56, 582-586 (10.1002/anie.201610534).

88. Eugenia Vasileiadou, Panagiotis A. Angaridis, Raphael G. Raptis and Logesh Mathivathanan, “Crystal structure of aquabis(2,2'-bipyridine-κ;N,N')chloridonickel(II) chloride chloroform solvate hemihydrate”, IUCrData. 2016, (10.1107/S2414314616018344).

87. Sam Kavoosi, Ramanjaneyulu Rayala, Brenna Walsh, Maria Barrios, Walter G. Gonzalez, Jaroslava Miksovska, Logesh Mathivathanan, Raphael G. Raptis, Stanislaw F. Wnuk, “8-(1,2,3-Triazol-1-yl)-7-deazapurine nucleosides”, Tetrahedron Lett. 2016, 57, 4364-4367 (doi: 10.1016/j.tetlet.2016.08.053).

86. Yong Liang, Sazzad H. Suzol, Zhiwei Wen, Alain G. Artiles, Logesh Mathivathanan, Raphael G. Raptis and Stanislaw F. Wnuk, “Uracil Nucleosides with Reactive Group at C5 position: 5-(1-Halo-2-sulfonylvinyl)uridine Analogues”, Org. Lett., 2016, 1 8, 1418-1421 (doi: 10.1021/acs.orglett.6b00346).

85. Logesh Mathivathanan, Raquel Cruz, Raphael G. Raptis, “[Cu3(μ3-O)]-pyrazolato metallacycle with terminal nitrate ligands”, Acta Crystallogr. E, 2016, E72, 492-494 (doi: 10.1107/S2056989016003741).

84. Logesh Mathivathanan, Karrar Al-Ameed, Katerina Lazarou, Zdeněk Trávníček, Yiannis Sanakis, Radovan Herchel, John E. McGrady, Raphael G. Raptis, “A trigonal prismatic Cu6-pyrazolato complex containing a μ6-F ligand”, Dalton Trans. 2015, 44, 20685-20691 (doi: 10.1039/c5dt03892h).

83. Xin-Yi Cao, Jeremiah W. Hubbard, Jennifer Guerrero-Medina, Arturo J. Hernández-Maldonado, Logesh Mathivathanan, Carlos Rinaldi, Yiannis Sanakis, Raphael G. Raptis “Spin-Glass Behavior of a Hierarchically-Organized, Hybrid Microporous Material, Based on an Extended Framework of Octanuclear Iron-Oxo Units”, Dalton Trans. 2015, 44, 3399-3409 (doi: 10.1039/c4dt02606c).

82. Ekaterina M. Zueva, Radovan Herchel, Serguei A. Borshch, Evgen V. Govor, W. M. C. Sameera, Ross McDonald, John Singleton, J. Krzystek, Zdeněk Trávníček, Yiannis Sanakis, John E. McGrady, Raphael G. Raptis “Double exchange in a mixed-valent octanuclear iron cluster, [Fe8(μ4-O)4(μ-4-Cl-pz)12Cl4]– ”, Dalton Trans. 2014, 43, 11269-11276 (doi: 10.1039/c4dt00020j).

81. Ramonita Dıaz-Ayala, Lisandra Arroyo-Ramırez, Raphael G. Raptis, Carlos R. Cabrera, “Thermal and surface analysis of palladium pyrazolates molecular precursors”, J. Therm. Anal. Calorim. 2014, 115, 479-488 (doi: 10.1007/s10973-013-3325-7).

80. Guang Yang, Juan A. Santana, Milton E. Rivera-Ramos, Jose J. Saavedra-Arias, Yasuyuki Ishikawa, Arturo J. Hernández-Maldonado, Raphael G. Raptis, “A Combined Experimental and Theoretical Study of Gas Sorption on Nanoporous Silver Triazolato Metal-Organic Frameworks”, Micropor. Mesopor. Mat. 2014, 183, 62-68 (doi: 10.1016/j.micromeso.2013.2013.09.006).

79. Lisandra Arroyo-Ramírez, Raphael G. Raptis, Carlos R. Cabrera, “Surface analysis and electrochemical characterization of palladium–cobalt nanoring formation from molecular precursor, [Et3NH]2[CoPd2(μ-4-I-3,5-Me2pz)4Cl4], on highly ordered pyrolytic graphite”, Surf. Interface Anal. 2013, 45, 1760-1768 (doi: 10.1002/sia.5318).

78. Peng-Cheng Duan, Zhao-Yang Wang, Jing-Huo Chen, Guang Yang, and Raphael G. Raptis, “Trigonal prismatic Cu(I) and Ag(I) pyrazolato nanocage hosts: encapsulation of S8 and hydrocarbon guests”, Dalton Trans. 2013, 42, 14951-14954 (doi:10.1039/c3dt51332g).

77. Lisandra Arroyo-Ramirez, Rubenier Montano-Serrano, Tatiana Luna-Pineda, Felix R. Roman, Raphael G. Raptis, Carlos R. Cabrera, “Synthesis and Characterization of Palladium and Palladium Cobalt Nanoparticles on Vulcan XC-72R for Oxygen Reduction Reaction”, ACS Appl. Mat. Interf. 2013, 5, 11603-11612 (doi:10.1021/am402932h).

76. Logesh Mathivathanan, Jorge Torres-King, José N. Primera-Pedrozo, Omar J. García-Ricard, Arturo J. Hernández-Maldonado, Juan A. Santana, Raphael G. Raptis, “Selective CO2 adsorption on metal-organic frameworks based on trinuclear Cu3-pyrazolato complexes: An experimental and computational study”, Cryst. Growth Des. 2013, 13, 2628-2635 (doi:10.1021/cg400382k).

75. Guang Yang, Peter Baran, Angel R. Martínez, Raphael G. Raptis, “Substitution Effects on the Supramolecular Aggregation of AgI-Pyrazolato Trimers”, Cryst. Growth Des. 2013, 13, 264-269 (doi:10.1021/cg301411j).

74. Evgen V. Govor, Indranil Chakraborty, Dalice M. Piñero, Peter Baran, Yiannis Sanakis, Raphael G. Raptis, “Structural and 57Fe-Mössbauer Characterization of Mononuclear Ferrous and Ferric Pyrazole Complexes”, Polyhedron 2012, 45, 55-60 (doi: 10.1016/j.poly.2012.07.052).

73. Logesh Mathivathanan, Marlyn Rivera-Carrillo, Raphael G. Raptis, “Three New Multinuclear Motifs in Cu(II)-pyrazolato Chemistry”, Inorg. Chim. Acta 2012, 391, 201-205 (doi: 10.1016/j.ica.2012.05.027).

72. Soma Das, Indranil Chakraborty, Dmitry Skachkov, Majid Ahmadi, Yasuyuki Ishikawa, Peter Baran, Raphael G. Raptis, “Water-Soluble Derivatives of Octanuclear Iron-Oxo-Pyrazolato Complexes; An Experimental and Computational Study”, Eur. J. Inorg. Chem. 2012, 3704-3711 (doi:10.1002/ejic.201200428).

71. W. M. C. Sameera, Dalice M. Piñero, Radovan Herchel, Yiannis Sanakis, John E. McGrady, Raphael G. Raptis, Ekaterina M. Zueva, “A Combined Experimental and Computational Study of the Magnetic Superexchange within a Triangular FeIII3(µ3-O)-Pyrazolato Complex”, Eur. J. Inorg. Chem. 2012, 3500-3506 (doi:10.1002/ejic.201200206).

70. Guang Yang, Peng-Cheng Duan, Kai-Ge Shi, Raphael G. Raptis, “Relaying isomerism from ligands to metal complexes: synthesis and structures of four isomeric binary silver(I) 3,5-dibutyl-1,2,4-triazolates”, Cryst. Growth Des. 2012, 12, 1882-1889 (doi:10.1021/cg201535x).

69. Ekaterina M. Zueva, W. M. C. Sameera, Dalice M. Piñero, Indranil Chakraborty, Eamonn Devlin, Peter Baran, Katarina Lebruskova, Yiannis Sanakis, John E. McGrady, Raphael G. Raptis, “Experimental and theoretical Mössbauer study of an extended family of [Fe8(µ4-O)4(µ-4-R-px)12X4] clusters”, Inorg. Chem. 2011, 50, 1021-1029 (doi:10.1021/ic101691q).

68. Lisandra Arroyo-Ramírez, Haralampos N. Miras, Raphael G. Raptis, Carlos R. Cabrera, Mater. Res. Soc Proc. 2010, 131 2, 1213-T10-01.

67. Jim Klostergaard, Kenia Parga, Raphael G. Raptis, “Current and Future Applications of Magnetic Resonance Imaging (MRI) to Breast and Ovarian Cancer Patient Management”, P. R. Health Sci. J. 2010, 29, 223-231.

66. Yiannis Sanakis, Michael Pissas, J. Krzystek, Joshua Telser, Raphael G. Raptis, “Spin Relaxation in a Ferromagnetic Triangular Cu3 Complex”, Phys. Chem. Lett. 2010, 493, 185-190 (doi:10.1016/j.cplett.2010.05.011).

65. Marlyn Rivera-Carrillo, Indranil Chakraborty, Raphael G. Raptis, “Systematic Synthesis of a Metal Organic Framework Based on Triangular Cu3(μ3-OH) Secondary Building Units: From a 0-D Complex, to an 1-D Chain and a 3-D Lattice”, Cryst. Growth Des. 2010, 10, 2606-2612 (doi:10.1021/cg100060p).

64. Guillermo Ferraudi, Dalice Piñero, Indranil Chakraborty, Raphael G. Raptis, A. Graham Lappin, Nicolas Berlin, “Mechanistic and energetic aspects of the thermal and photochemical redox chemistry of the octanuclear cubane complexes, FeIII8(μ4-O4)(μ-pyrazolate)12X4 (X = Cl or Br)”, J. Phys. Chem. A 2010, 114, 5702-5709 (doi:10.1021/jp911644e).

63. Haralampos Miras, Indranil Chakraborty, Raphael G. Raptis, “Tri-, deca- and dodecanuclear Co(III)-pyrazolate metallacycles”, Chem. Commun. 2010, 46, 2569-2571 (doi:10.1039/b920486e).

62. Xiaomei Wei, Abimael D. Rodrguez, Peter Baran, Raphael G. Raptis, “Dolabellane-Type Diterpenoids with Antiprotozoan Activity from a Southwestern Caribbean Gorgonian Octocoral of the Genous Eunicia”, J. Nat. Prod. 2010, 73, 925-934 (doi:10.1021/np100074r).

61. Konstantinos D. Demadis, Eleni Barouda, Hong Zhao, Raphael G. Raptis, “Structural architectures of charge-assisted, hudrogen-bonded, 2D layered amine…tetraphosphonate and zinc….tetraphosphonate ionic materials”, Polyhedron 2009, 28, 3361-3367 (doi:10.1016/j.poly.2009.05.050).

60. Ekaterina M. Zueva, Maria M. Petrova, Radovan Herchel, Zdenek Trávnícek, Raphael G. Raptis, Logesh Mathivathanan, John E. McGrady, “Electronic structure and magnetic properties of a trigonal prismatic CuII6 cluster”, Dalton Trans. 200 9, 5924-5932 (doi:10.1039/b907805c).

59. Jan Vicente, Brunilda Vera, Abimael D. Rodríguez, Idaliz Rodríguez-Escudero, Raphael G. Raptis, “Euryjanicin A: a new cycloheptapeptide from the Caribbean marine sponge Prosuberites laughlini”, Tetrahedron Lett. 2009, 50, 4571-4574 (doi:10.1061/j.tetlet.2009.05.067).

58. Joseph Gallegos, A. H. Francis, Nathan W. Ockwig, Paul G. Rasmussen, Raphael G. Raptis, Paul R. Challen, Issouf Ouedraogo, “The Spectroelectrochemical, Magnetic, and Structural Characterization of Reduced Hexaazatriphenylenehexacarbonitrile, HAT(CN)6”, Synth. Met. 2009, 159, 1667-1671 (doi:10.1016/j.synthmet.2009.05.004).

57. Lisandra Arroyo-Ramírez, Rubenier Montano-Serrano, Raphael G. Raptis, Carlos C. Cabrera, “Nanostructural Formation of Pd-Co Bimetallic Complex on HOPG Surfaces: XPS and AFM Studies”, Res. Lett. Nanotech. 2009, Article ID 971423 (5 pages) (doi:10.1155/2009/971423).

56. Guang Yang, Raphael G. Raptis, “Dinuclear gold(III) pyrazolato complexes – synthesis, structural characterization and transformation to their trinuclear gold(I) and gold(I/III) analogues”, Inorg. Chim. Acta, 2009, 362, 1546-1552 (doi:10.1016/j.ica.2008.07.028).

55. Konstantinos Demadis, Eleni Barouda, Raphael G. Raptis, Hong Zhao, “Metal Tetraphosphonate “Wires” and Their Corrosion Inhibiting Passive Films”, Inorg. Chem. 2009, 48, 819-821 (doi:10.1021/ic8021084).

54. Indranil Chakraborty, Peter Baran, Yiannis Sanakis, A. Simopoulos, Esteban Fachini, Raphael G. Raptis, “A Mixed-Valence Octanuclear Iron-Oxo Pyrazolate: Assessment of Electronic Delocalization by Structural and Spectroscopic Analysis”, Inorg. Chem. 2008, 47, 11734-11737 (doi:10.1021/ic801459s).

53. Catherine Gabriel, Melita Menelaou, Markos Daskalakis, Andrea Lakatos, Tamas Kis, Constantin Mateescu, Raphael G. Raptis, Panagiotis Zoumpoulakis, Athanasios Salifoglou, “Synthetic, structural, spectroscopic and solution speciation studies of the binary Al(III)-quinic acid system. Relevance of soluble Al(III)-hydroxycarboxylate species to molecular toxicity”, Polyhedron 2008, 27, 2911-2920.

52. Haralampos N. Miras, Hong Zhao, Radovan Herchel, Carlos Rinaldi, Raphael G. Raptis, “Synthesis and Characterization of Linear Trinuclear Pd, Co and Pd/Co Pyrazolate Complexes”, Eur. J. Inorg. Chem. 2008, 30, 4745-4755 (doi: 10.1002/ejic.200800349).

51. Haralampos N. Miras, Daniel J. Stone, Eric J. L. McInnes, Raphael G. Raptis, Peter Baran, George I. Chilas, Michael P. Sigalas, Themistoklis A. Kabanos, Leroy Cronin, “Solution Discovery and Solid State Characterisation of a Heterometallic Polyoxometalate {Mo11V7}: [MoVI11VV5VIV2O52(μ9-SO3)]7-”, Chem. Commun. 2008, 4703-4705 (doi: 10.1039/b811279g).

50. Marlyn Rivera-Carrillo, Indranil Chakraborty, Gellert Mezei, Richard D. Webster, Raphael G. Raptis, “Tuning of the [Cu3(μ-O)]4+5+ Redox Couple; Spectroscopic Evidence of Charge Delocalization in the Mixed-Valent [Cu3(μ-O)]5+ Species”, Inorg. Chem. 2008, 47, 7644-7650 (doi: 10.1021ic800531y).

49. Konstantinos D. Demadis, Maria Papadaki, Raphael G. Raptis, Hong Zhao, “Corrugated, Sheet-Like Architectures in Layered Alkaline-Earth Metal R,S-Hydroxyphosphonoacetate Frameworks: Applications for Anti-Corrosion Protection of Metal Surfaces”, Chem. Mater. 2008, 20, 4835-4846 (doi: 10.1021/cm801004w).

48. Jeffrey Marrero, Jaime Benitez, Abimael D. Rodríguez, Hong Zhao, Raphael G. Raptis, “Bipinnatins K-Q, minor cembrane-type diterpenes from West Indian gorgonian Pseudopterogorgia kallos: Isolation, structure assignment, and evaluation of biological activities”, J. Nat. Prod. 2008, 71, 381-389 (doi: 10.1021/np0705561).

47. Guang Yang, Raphael G. Raptis, Peter Šafář, “Cadmium(II) complexes of 4-(4-pyridyl)pyrazole; Conformational supramolecular isomerism in a ‘two-in-one’ crystal”, Cryst. Growth Des. 2008, 8, 981-985 (doi: 10.1021/cg700935x).

46. Konstantinos D. Demadis, Maria Papadaki, Raphael G. Raptis, Hong Zhao, “2D and 3D alkaline earth metal carboxyphosphonate hybrids: Anti-corrosion coatings for metal surfaces”, J. Solid State Chem. 2008, 181, 679-683.

45. Peter Baran, Roman Boča, Indranil Chakraborty, John Giapintzakis, Radovan Herchel, Qing Huang, John E. McGrady, Raphael G. Raptis, Yiannis Sanakis, Athanasios Simopoulos, “Synthesis, Characterization and Study of Octanuclear Iron-Oxo Clusters Containing a Redox-Active Fe4O4-Cubane Core”, Inorg. Chem. 2008, 47, 645-655 (doi: 10.1021/ic7020337).

44. Dalice Piñero, Peter Baran, Roman Boča, Radovan Herchel, Michael Klein, Raphael G. Raptis, Franz Renz, Yiannis Sanakis, “Pyrazolate-Supported Fe3(μ3-O)-Core; Structural, Spectroscopic, Electrochemical and Magnetic Study”, Inorg. Chem. 2007, 46, 10981-10989 (doi: 10.1021/ic0701460).

43. Claudia A. Ospina, Abimael D. Rodríguez, Hong Zhao, Raphael G. Raptis, “Bipinnaptolide B, a bioactive oxapolycyclic diterpene from the Colombian gorgonian coral Pseudopterogorgia bipinnata”, Tetrahedron Lett. 2007, 48, 7520-7523 (doi: 10.1016/j.tetlet.2007.08.069).

42. Gellert Mezei, Marlyn Rivera-Carillo, Raphael G. Raptis, “Trigonal prismatic CuII6-pyrazolato cages: Structural and electrochemical study, evidence of charge-delocalisation”, Dalton Trans. 2007, 37-40 (doi: 10.1039/b615018g).

41. Guang Yang, Raphael G. Raptis, “Synthesis and crystal structure of tetrameric silver(I) 3,5-di-tert-butyl-pyrazole”, Inorg. Chim. Acta 2007, 360, 2503-2506 (doi:10.1016/j.ica.2006.10.032).

40. Anca Mateescu, Catherine Gabriel, Raphael G. Raptis, Peter Baran, Athanasios Salifoglou, “pH-Specific synthesis, spectroscopic, and structural characterization of an assembly of species between Co(II) and N,N-bis(phosphonomethyl)glycine. Gaining insight into metal-ion phosphonate interactions in aqueous Co(II)-organophosphonate systems”, Inorg. Chim. Acta 2007, 360, 638-648.

39. Gellert Mezei, Raphael G. Raptis, Joshua Telser, “Trinuclear, Antiferromagnetically Coupled CuII Complexes with an EPR Spectrum of Mononuclear CuII: Effect of Alcoholic Solvents”, Inorg. Chem. 2006, 45, 8841-8843 (doi: 10.1021/ic061186r).

38. Konstantinos D. Demadis, Panagiotis Lykoudis, Raphael G. Raptis, Gellert Mezei, “Phosphonopolycarboxylates as Chemical Additives for Calcite Scale Dissolution and Metallic Corrosion Inhibition Based on Calcium-Phosphonotricarboxylate Organic-Inorganic Hybrid”, Cryst. Growth Des. 2006, 8, 1064-1067 (doi: 10.1021/cg050620h).

37. Konstantinos D. Demadis, Stella D. Katarachia, Raphael G. Raptis, Hong Zhao, Peter Baran, “Alkali Earth Metal Triphosphonates: Inorganic-Organic Polymeric Hybrids from Dication-Dianion Association”, Cryst. Growth Des. 2006, 8, 836-838 (doi: 10.1021/cg0506368).

36. Ramonita Díaz-Ayala, Esteban R. Fachini, Raphael G. Raptis, Carlos R. Cabrera, Langmuir 2006, 22, 101185-.

35. Konstantinos D. Demadis, Raphael G. Raptis, Peter Baran, “Chemistry of Organophosphonate Scale Growth Inhibitors: 2. Structural Aspects of 2-Phosphonobutane-1,2,4-Tricarboxylic Acid Monohydrate (PBTC.H2O)”, Bioinorg. Chem. Appl. 2005, 3, 119-134.

34. Gellert Mezei, John E. McGrady, Raphael G. Raptis, “First Structural Characterization of a Delocalized, Mixed-Valent, Triangular Cu37+ Species: Chemical and Electrochemical Oxidation of a CuII3(μ3-O) Pyrazolate and Electronic Structure of the Oxidation Product”, Inorg. Chem. 2005, 44, 7271-7273 (doi: 10.1021/ic050729e).

33. Konstantinos D. Demadis, Christos Mantzaridis, Raphael G. Raptis, Gellert Mezei, “Metal-Organophosphonate Inorganic-Organic Hybrids: Crystal Structure and Anticorrosion Effects of Zinc Hexamethylenediaminetetrakis(methylenephosphonate) on Carbon Steels”, Inorg. Chem. 2005, 44, 4469-4471 (doi: 10.1021/ic050572q).

32. Haralampos N. Miras, Raphael G. Raptis, Peter Baran, Nikolia Lalioti, Andrew Harrison, Themistoklis A. Kabanos, “A novel compound with a 1D network structure constructed by [(VIVO)6(μ4-O)2(μ3-OH)2(μ3-SO3)42-SO32- and 4,4’-bipyridine components: its synthesis, characterization, and magnetic behavior”, C. R. Chimie/, 2005, 8, 957-962.

31. Haralampos N. Miras, Raphael G. Raptis, Nikolia Lalioti, Michael P. Sigalas, Peter Baran, Themistoklis A. Kabanos, “A Novel Series of Vanadium-Sulfite Polyoxometalates: Synthesis, Structural, and Physical Studies”, Chem. Eur. J. 2005, 11, 2295-2306.

30. Angel A. Martí, Gellert Mezei, Lorena Maldonado, Giovanni Paralitici, Raphael G. Raptis; Jorge L. Colón, "Structural and Photophysical Characterization of fac-tricarbonylchloro-1,10-phenanthroline-5,6-epoxydirhenium(I)", Eur. J. Inorg. Chem. 2005, 118-124.

29. Ramonita Díaz-Ayala, Raphael Raptis, Carlos R. Cabrera, “Formation of Palladium Nanoparticles and Others Structures from Molecular Precursors: a Microscopy and Spectroscopy Study”, Rev. Adv. Mater. Sci. 2005, 10, 375-380.

28. D. Berkes, A. Kolarovic, R. G. Raptis, P. Baran, “Absolute structure determination of (2R, 1’S)-2-(1’-benzyl-2’-hydroxyethylamino)-4-phenylbutanoic acid”, J. Mol. Struct. 2004, 697, 101-107 (doi: 10.1016/j.molstruc.2004.04.001).

27. X. Wei, A. D. Rodríguez, P. Baran, R. G. Raptis, J. A. Sánchez, E. Ortega-Barria, J. González, “Antiplasmodial Cembradiene Diterpenoids from a Southwestern Caribbean Gorgonian Octocoral of the Genus Eunicea”, Tetrahedron 2004, 60, 11813-11819 (doi: 10.1016/j.tet.2004.09.108).

26. Guang Yang, Raphael G. Raptis, “A robust, porous, cationic silver(I) 3,5-diphenyl-1,2,4-triazolate framework with a new uninodal 49.66 net”, Chem. Commun. 2004, 2058-2059 (doi: 10.1039/b404269g).

25. Ramonita Díaz-Ayala, Lisandra Arroyo, Raphael G. Raptis, Carlos R. Cabrera, “Thermal Reduction of Pd Molecular Cluster Precursors at Highly Ordered Pyrolytic Graphite Surfaces”, Langmuir 2004, 20, 8329-8335 (doi: 10.1021/la0364688).

24. Gellert Mezei, Marlyn Rivera-Carrillo, Raphael G. Raptis, “Effect of copper-substitution on the structure and nuclearity of Cu(II)-pyrazolates: from trinuclear to tetra-, hexa- and polynuclear complexes”, Inorg. Chim. Acta 2004, 357, 3721-3732 (doi: 10.1016/j.ica.2004.05.022).

23. Gellert Mezei, Raphael G. Raptis, “Effect of pyrazole-substitution on the structure and nuclearity of Cu(II)-pyrazolates”, Inorg. Chim. Acta 2004, 357, 3279-3288 (doi: 10.1016/j.ica.2004.03.016).

22. Jeffrey Marrero, Abimael D. Rodríguez, Peter Baran, Raphael G. Raptis, J. A. Sánchez, E. Ortega-Barria; T. L. Capson, “Bielschowskysin, a Gorgonian-Derived Biologically Active Diterpene with an Unprecedented Carbon Skeleton”, Org. Lett. 2004, 6, 1661-1664 (doi: 10.1021/ol049495d).

21. Jeffrey Marrero, Abimael D. Rodríguez, Peter Baran, Raphael G. Raptis, “Ciereszkolide: Isolation and Structure Characterization of a Novel Rearranged Cembrane from the Caribbean Sea Plume Pseudopterogorgia kallos”, Eur. J. Org. Chem. 2004, 3909-3912.

20. Gellert Mezei, Peter Baran, Raphael G. Raptis, “Anion Encapsulation by Neutral Supramolecular Assemblies of Cyclic CuII-Complexes; a Series of Five Polymerization Isomers, [cis-CuII(μ-OH)(μ-pz)]n, n = 6, 8, 9, 12, 14”, Angew. Chem. Int. Ed. 2004, 43, 574-577 (doi: 10.1002/anie.200352636).

19. Margarita Ortiz-Marciales, Mélvin De Jesús, Eduvígis González, Raphael G. Raptis, Peter Baran, “A 1,3,2-oxazaborolidine dimer derived from (S)-a,a-diphenylprolinol”, Acta Crystallogr. 2004, C60, 173-175.

18. Haralampos N. Miras, J. Derek Woollins, Alexandra M. Slawin, Raphael Raptis, Peter Baran, Themistoklis A. Kabanos, “A novel polyoxo(thio)molybdenum(V) sulfite compound: Synthesis and crystal structure of {[Mo2V(μ-S)2O2]6(μ3-SO3)4(μ-SO3)12}20- anion”, Dalton Trans. 2003, 3668-3670.

17. Roman Boča, L. Dhlan, Gellert Mezei, Tamara Ortiz-Pérez, Raphael G. Raptis, Joshua Telser, “Trinuclear Ferromagnetically Coupled CuII-Pyrazolato Complexes as Models of Particulate Methane Monooxygenase (pMMO)”, Inorg. Chem. 2003, 42, 5801-5803 (doi: 10.1021/ic0344416).

16. Gellert Mezei, Raphael G. Raptis, “Pyrazole-4-sulphonate networks of alkali and alkaline earth metals. Effects of cation size, charge, H-bonding and aromatic interactions on the three-dimencional supramolecular architecture”, New J. Chem. 2003, 9, 1399-1407 (doi: 10.1039/b303096b).

15. Guang Yang, Raphael G. Raptis, “Synthesis, characterization and crystal structures of two 2-naphthyl substituted pyrazoles”, J. Heterocyclic Chem. 2003, 40, 659-664.

14. Guang Yang, Raphael G. Raptis, “Synthesis, structure and properties of tetrameric gold(I) 3,5-di-tert-butyl-pyrazolate”, Inorg. Chim. Acta 2003, 352, 98-104, (issue dedicated to Prof. Martin A. Bennett).

13. Peter Baran, Raphael G. Raptis, Abimael D. Rodríguez, Ileana I. Rodríguez, Yan-Ping Shi, “Structural Characterization of Elisabatin B and Elisabatin C”, J. Chem. Crystallogr. 2003, 33, 711-718 (doi: 10.1023/A:1025349727512).

12. Guang Yang, Raphael G. Raptis, “Supramolecular assembly of trimeric gold(I) pyrazolates through aurophilic attractions”, Inorg. Chem. 2003, 42, 261-263 (doi: 10.1021/ic026051+).

11. Jeffrey Marrero, Abimael D. Rodríguez, Peter Baran, Raphael G. Raptis, “Isolation and Structure of Providencin: A Highly Oxygenated Diterpene Possessing a Unique Bicyclo[12.2.0]hexadecane Ring System from the Sea Plume Pseudopterogorgia kallos”, Org. Lett. 2003, 5, 2551-2558 (doi: 10.1021/ol034854a).

10. Jeffrey Marrero, Abimael D. Rodríguez, Peter Baran, Raphael G. Raptis, “Isolation and Cheracterization of Kallosin A, a Novel Rearranged Pseudopterane Diterpenoid from the Carribean Sea Plume Pseudopterogorgia kallos (Bielschowsky)”, J. Org. Chem. 2003, 68, 4977-4979 (doi: 10.1021/jo0343329).

9. Yan-Ping Shi, Abimael D. Rodriguez, Charles L. Barnes, Juan A. Sanchez, Raphael G. Raptis, Peter Baran. “New terpenoid constituents from Eunicea pinta”, J. Nat. Prod. 2002, 65, 1232-1241 (doi: 10.1021/np0200820).

8. Guang Yang, Raphael G. Raptis, “Oxidation of gold(I)-pyrazolates by aqua regia. X-ray crystal structures of the first examples of trinuclear AuIII3 and AuIAuIII2 pyrazolato complexes”, Dalton Trans. 2002, 3936-3938 (doi: 10.1039/b207600d).

7. Peter Baran, Cruz M. Marrero, Soribel Pérez, Raphael G. Raptis, “Stepwise ring-closure synthesis and structural characterization of a homoleptic palladium(II)-pyrazolato cyclic trimer”, Chem. Commun. 2002, 1012-1013.

6. Panagiotis A. Angaridis, Peter Baran, R. Boča, Francisco Cervantes-Lee, W. Haase, Gellert Mezei, Raphael G. Raptis, R. Werner, “Synthesis and Structural Characterization of Trinuclear CuII-Pyrazolato Complexes Containing μ3-OH, μ3-O and μ3-Cl Ligands. Magnetic Susceptibility Study of [PPN]2[(μ3-O)Cu3(μ-pz)3Cl3]”, Inorg. Chem. 2002, 41, 2219-2228 (doi: 10.1021/ic010670l).

5. Konstantinos D. Demadis, John D. Sallis, Raphael G. Raptis, Peter Baran, “A Crystallographically Characterized Nine-Coordinate Calcium-Phosphocitrate Complex as in vivo Calcification Inhibitor”, J. Am. Chem. Soc. 2001, 123, 10129-10130.

4. Raphael G. Raptis, Irene P. Georgakaki, David C. R. Hockless, "First Example of a Ferric/Oxygen-Cubane; an Octanuclear Complex of T-Symmetry, Stable Over Five Oxidation States", Angew. Chem., Int. Ed. 1999, 38, 1632-1634.

3. Silvia Cortez, Raphael G. Raptis, "Silver 1995", Coord. Chem. Rev. 1998, 169, 363-426.

2. Silvia Cortez, Raphael G. Raptis, "Silver 1994", Coord. Chem. Rev. 1997, 162, 495-538.

1. Lai Yoong Goh, Meng S. Tay, Ekkehard Sinn, Raphael G. Raptis, "Variable Temperatrure NMR Study and Reductively-Induced Isomerization and Degradation of [CpCr(CO)2(μ-SPh)]2. Crystal Structure of Cp2Co[CpCr(SPh)3]", J. Organomet. Chem. 1996, 524, 31-40.